NEETChemistrySome Basic Concepts of Chemistry
Assertion (A): 12.5 g of an impure sample of magnesium carbonate ( MgCO ₃ ) requires 100 mL of 2.0 M HCl for complete reaction, so its percentage purity is 84 % . Reason (R): The balanced chemical equation for the reaction is MgCO ₃ + 2 HCl MgCl ₂ + H ₂ O + CO ₂ and the molar mass of MgCO ₃ is 84 g mol ⁻¹ . In the light of the above statements, choose the most appropriate answer from the options given below:
Options
- AAssertion (A) is false but Reason (R) is true.
- BBoth Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of Assertion (A).
- CBoth Assertion (A) and Reason (R) are true but Reason (R) is not the correct explanation of Assertion (A).
- DAssertion (A) is true but Reason (R) is false.
Correct answer
A. Assertion (A) is false but Reason (R) is true.
Step-by-step solution
Moles of HCl used = Molarity Volume (in L) = 2.0 0.100 = 0.2 mol From the balanced equation given in the Reason: MgCO ₃ + 2 HCl MgCl ₂ + H ₂ O + CO ₂ 2 mol of HCl reacts with 1 mol of MgCO ₃ . So, 0.2 mol of HCl will react with 0.1 mol of pure MgCO ₃ . Mass of pure MgCO ₃ required = Moles Molar mass = 0.1 84 = 8.4 g Percentage purity of the sample = ( Mass of pure substance Total mass of sample ) 100 = ( 8.4 12.5 ) 100 = 67.2 % The Assertion claims the percentage purity is 84 % , which is incorrect. Hence, Assertio