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NEETChemistrySome Basic Concepts of Chemistry

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): 10 g of O ₂ gas contains more molecules than 10 g of O ₃ gas, but both samples contain the same total number of oxygen atoms. Reason (R): For a given mass of allotropes, the number of molecules is inversely proportional to the molar mass, but the total number of atoms depends only on the given mass

Options

  1. ABoth Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of Assertion (A)
  2. BBoth Assertion (A) and Reason (R) are true but Reason (R) is not the correct explanation of Assertion (A)
  3. CAssertion (A) is true but Reason (R) is false
  4. DAssertion (A) is false but Reason (R) is true

Correct answer

A. Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of Assertion (A)

Step-by-step solution

Assertion (A) is true: Number of molecules = Given mass Molar mass N_A . For 10 g of O ₂ , molecules = 10 32 N_A . For 10 g of O ₃ , molecules = 10 48 N_A . Thus, O ₂ has more molecules. The number of atoms in O ₂ = 10 32 2 N_A = 10 16 N_A . The number of atoms in O ₃ = 10 48 3 N_A = 10 16 N_A . Both contain the same number of atoms. Reason (R) is true and explains (A): For a given mass w of an allotrope with atomicity x and atomic mass M_a , the molar mass is x M_a . The number of molecules is w x M_a N_A , which

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