NEET2017ChemistryPolymersActual
Arrange the following monomers in order of decreasing ability to undergo cationic polymerisation. I. CH ₂= CH - C ₆ H ₄ ( NO ₂ ) II. CH ₂= CH - C ₆ H ₄ ( CH ₃ ) III. CH ₂= CH - C ₆ H ₄ ( OCH ₃ )
Options
- AI > II > III
- BII > I > III
- CIII > II > I
- DI > III > II
Correct answer
C. III > II > I
Step-by-step solution
Electron releasing groups such as - CH ₃,- OCH ₃ activate the monomer towards cationic polymerisation because these groups provide stability to the carbocation formed. On the other hand, - NO ₂ is a electron withdrawing group. So, it reduces the stability of carbocation formed. Thus, the correct order is