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NEET2017ChemistryPolymersActual

Arrange the following monomers in order of decreasing ability to undergo cationic polymerisation. I. CH ₂= CH - C ₆ H ₄ ( NO ₂ ) II. CH ₂= CH - C ₆ H ₄ ( CH ₃ ) III. CH ₂= CH - C ₆ H ₄ ( OCH ₃ )

Options

  1. AI > II > III
  2. BII > I > III
  3. CIII > II > I
  4. DI > III > II

Correct answer

C. III > II > I

Step-by-step solution

Electron releasing groups such as - CH ₃,- OCH ₃ activate the monomer towards cationic polymerisation because these groups provide stability to the carbocation formed. On the other hand, - NO ₂ is a electron withdrawing group. So, it reduces the stability of carbocation formed. Thus, the correct order is

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