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Practical Chemistry

NEET · Chemistry · Practical Chemistry

Consider the following statements regarding the preliminary tests...

Consider the following statements regarding the preliminary tests of anions with dilute H2SO4\text{H}_2\text{SO}_4:

I. A carbonate salt gives a colourless and odourless gas that turns lime water milky.
II. A sulphide salt evolves a gas with a pungent smell of burning sulphur.
III. A sulphite salt evolves a gas that turns acidified potassium dichromate paper green.
IV. A nitrite salt yields a colourless gas which turns into reddish-brown fumes on contact with air.

How many of the above statements are correct?

Options

  1. AOne
  2. BTwo
  3. CFour
  4. DThree

Correct answer

D. Three

Step-by-step solution

Statement I is correct: Carbonate salts react with dilute H2SO4\text{H}_2\text{SO}_4 to evolve CO2\text{CO}_2 gas, which is colourless, odourless, and turns lime water milky.

Statement II is incorrect: Sulphide salts evolve H2S\text{H}_2\text{S} gas, which has a characteristic smell of rotten eggs. The pungent smell of burning sulphur is a characteristic of SO2\text{SO}_2 gas (evolved from sulphites).

Statement III is correct: Sulphite salts evolve SO2\text{SO}_2 gas, which is a reducing agent and turns acidified potassium dichromate paper green due to the formation of Cr3+\text{Cr}^{3+} ions.

Statement IV is correct: Nitrite salts react with dilute acids to yield nitric oxide (NO\text{NO}), which is colourless but rapidly oxidises in air to form reddish-brown fumes of nitrogen dioxide (NO2\text{NO}_2).

Therefore, three statements (I, III, and IV) are correct.

Answer: Three
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