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BITSAT2024ChemistryAldehydes and KetonesActual

Which of the following compounds will undergo self aldol condensation in the presence of cold dilute alkali?

Options

  1. ACH ₂= CH - CHO
  2. BCH C - CHO
  3. CC ₆ H ₅ CHO
  4. DCH ₃ CH ₂ CHO

Correct answer

D. CH ₃ CH ₂ CHO

Step-by-step solution

Aldehydes which contain -hydrogen on a saturated carbon, i.e. CH ₃ CH ₂ CHO will undergo aldol condensation. Although CH ₂= C H - CHO also contain a -hydrogen atom but cannot be easily abstracted by a base to form a carbanion and hence does not undergo aldol condensation.

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