Which of the following compound will give blood red colour while...

When nitrogen and sulphur both are present in the organic compound, they combine during fusion to form sodium thiocyanate (sulphocyanide).

Thus, the compounds containing both $N$ and $S$ give blood red colour in Lassaigne's test due to the formation of $Fe{\left(SCN\right)}_{2}$. Thus, ${H}_{2}N\left({C}_{6}{H}_{4}\right){SO}_{3}H$ gives blood red colour in Lassaigne's test of nitrogen.