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BITSAT 2017
Exam
BITSAT
Year
2017
Subject
Chemistry
Chapter
General Organic Chemistry

BITSAT 2017 · Chemistry · General Organic Chemistry

Which of the following compound does not follow Huckel's rule?&

Which of the following compound does not follow Huckel's rule?&Which of the following compound does not follow Huckel's rule?&Which of the following compound does not follow Huckel's rule?&Which of the following compound does not follow Huckel's rule?&Which of the following compound does not follow Huckel's rule?&

Options

  1. ABy what percentage will the transmission range of a TV tower be affected when the height of the tower is increased by
  2. BBy what percentage will the transmission range of a TV tower be affected when the height of the tower is increased by
  3. CBy what percentage will the transmission range of a TV tower be affected when the height of the tower is increased by
  4. DBy what percentage will the transmission range of a TV tower be affected when the height of the tower is increased by

Correct answer

D. By what percentage will the transmission range of a TV tower be affected when the height of the tower is increased by

Step-by-step solution

An aromatic compound can follow Huckel's rule if it has (4n+2)π( 4n + 2 ) \pi-electrons

where, n=n = integer 0,1,2,3,…0, 1, 2, 3, \ldots etc.

Thus,

(a) n=0;4×0+2=2πn = 0; 4 \times 0 + 2 = 2\pi

∴∴ follow Huckel's rule

(b) n=1;n = 1; Number of π\pi-electrons =6= 6

∴∴ follows Huckels rules.

(c) n=1;n = 1; Number of π\pi-electrons =6= 6

∴∴ follows Huckel's rule.

(d) n=1n = 1, Number of π\pi-electrons =8= 8

(4n+2=4×1+2=6)( 4n + 2 = 4 \times 1 + 2 = 6 )

but this compound has 88 electrons which distorts the plane and hence does not follows Huckel's rule.

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