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BITSAT2009ChemistryGeneral Organic ChemistryActual

The intermediate formed during the addition of HCl to propene in the presence of peroxide is

Options

  1. ACH ₃ CHCH ₂ CI
  2. BCH ₂ CHCH ₃
  3. CCH ₃ CH ₂ CH ₂
  4. DCH ₃ CH ₂ C H ₂

Correct answer

B. CH ₂ CHCH ₃

Step-by-step solution

The addition of HCl to propene proceeds by ionic mechanism and not by free radical mechanism. Hence it forms intermediate carbonium ion.

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