BITSAT2013ChemistryHaloalkanes and HaloarenesActual
In a S _ N 2 substitution reaction of the type R - Br + Cl ⁻ DMF R - Cl + Br ⁻ which one of the following has the highest relative rate?
Options
- ACH ₃- CH ₂- CH ₂ Br
- BCH ₃ CH ₂ Br
Correct answer
3
Step-by-step solution
S _ N 2 mechanism is followed in case of primary and secondary halides i.e., S _ N ² reaction is favoured by small groups on the carbon atom attached to halogens so