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BITSAT2013ChemistryHaloalkanes and HaloarenesActual

In a S _ N 2 substitution reaction of the type R - Br + Cl ⁻ DMF R - Cl + Br ⁻ which one of the following has the highest relative rate?

Options

  1. ACH ₃- CH ₂- CH ₂ Br
  2. BCH ₃ CH ₂ Br

Correct answer

3

Step-by-step solution

S _ N 2 mechanism is followed in case of primary and secondary halides i.e., S _ N ² reaction is favoured by small groups on the carbon atom attached to halogens so

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