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COMEDK20269 May 2026Morning ShiftChemistryAldehydes and KetonesActual

Which of the following is NOT TRUE about nucleophilic addition reactions of aldehydes?

Options

  1. AHemiacetals are gem-dialkoxy compounds
  2. BThe hydrogensulphite addition product is useful for separation and purification of aldehydes
  3. CAldehydes and ketones react very slowly with pure HCN to yield cyanohydrins
  4. D2,4 DNP derivatives are useful to identify aldehydes and ketones

Correct answer

A. Hemiacetals are gem-dialkoxy compounds

Step-by-step solution

Hemiacetals contain one alkoxy group ( -OR ) and one hydroxyl group ( -OH ) attached to the same carbon atom. They are gem-alkoxyalcohols. Acetals contain two alkoxy groups attached to the same carbon atom and are known as gem-dialkoxy compounds. Thus, the statement that hemiacetals are gem-dialkoxy compounds is incorrect. The sodium bisulphite addition product is crystalline and water-soluble, and can be converted back to the original carbonyl compound by treating it with dilute mineral acid or alkali. Therefore,

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