COMEDK20269 May 2026Morning ShiftChemistryAldehydes and KetonesActual
Which of the following is NOT TRUE about nucleophilic addition reactions of aldehydes?
Options
- AHemiacetals are gem-dialkoxy compounds
- BThe hydrogensulphite addition product is useful for separation and purification of aldehydes
- CAldehydes and ketones react very slowly with pure HCN to yield cyanohydrins
- D2,4 DNP derivatives are useful to identify aldehydes and ketones
Correct answer
A. Hemiacetals are gem-dialkoxy compounds
Step-by-step solution
Hemiacetals contain one alkoxy group ( -OR ) and one hydroxyl group ( -OH ) attached to the same carbon atom. They are gem-alkoxyalcohols. Acetals contain two alkoxy groups attached to the same carbon atom and are known as gem-dialkoxy compounds. Thus, the statement that hemiacetals are gem-dialkoxy compounds is incorrect. The sodium bisulphite addition product is crystalline and water-soluble, and can be converted back to the original carbonyl compound by treating it with dilute mineral acid or alkali. Therefore,