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COMEDK2024Evening ShiftChemistryChemical Bonding and Molecular StructureActual

Which of the following two molecular species are Diamagnetic in nature? [ A ]= O ₂⁻ [ B ] .= N ₂⁺ [ C ]= C ₂ [ D ]= O ₂ ²⁻

Options

  1. AB & C
  2. BA & B
  3. CC & D
  4. DD & A

Correct answer

C. C & D

Step-by-step solution

O₂^- (17e): _ 1s ^2 _ 1s ^ *2 _ 2s ^2 _ 2s ^ *2 _ 2p_z ^2 _ 2p_x ^2 _ 2p_y ^2 _ 2p_x ^ *2 _ 2p_y ^ *1 one unpaired electron, paramagnetic N₂^+ (13e): _ 1s ^2 _ 1s ^ *2 _ 2s ^2 _ 2s ^ *2 _ 2p_x ^2 _ 2p_y ^2 _ 2p_z ^1 one unpaired electron, paramagnetic C₂ (12e): _ 1s ^2 _ 1s ^ *2 _ 2s ^2 _ 2s ^ *2 _ 2p_x ^2 _ 2p_y ^2 all electrons paired, diamagnetic O₂²⁻ (18e): _ 1s ^2 _ 1s ^ *2 _ 2s ^2 _ 2s ^ *2 _ 2p_z ^2 _ 2p_x ^2 _ 2p_y ^2 _ 2p_x ^ *2 _ 2p_y ^ *2 all electrons paired, diamagnetic C₂ and O₂²⁻ are diamagnetic. Ans

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