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COMEDK2023ChemistryChemical Bonding and Molecular Structure

Which of these represents the correct order of decreasing bond order?

Options

  1. AC ₂²⁻> O ₂²⁺> O ₂⁻> He ₂²⁺
  2. BO ₂⁻> O ₂⁺> He ₂⁺> C ₂²⁻
  3. CHe ₂⁺> O ₂⁻> C ₂²⁻> O ₂⁺
  4. DHe ₂⁺> O ₂²⁻> O ₂⁺> O ₂⁻

Correct answer

A. C ₂²⁻> O ₂²⁺> O ₂⁻> He ₂²⁺

Step-by-step solution

aligned & He ₂⁺: 1 s^2, 1 s^1 & BO = 1 2 (N_b-N_a )= 1 2 (2-1)= 1 2 =0.5 & C ₂²⁻: 1 s^2, ^* 1 s^2, 2 s^2, ^* 2 s^2, ( 2 p_x^2 2 p_y^2 ), 2 p_z^2 & BO = 1 2 (10-4)= 6 2 =3.0 & O ₂⁺= 1 s^2, ^* 1 s^2, 2 s^2, ^* 2 s^2 2 p_z^2 ( 2 p_x^2 2 p_y^2 ), & BO = 1 2 (10-5)= 5 2 =2.5 & O ₂⁻= 1 s^2, ^* 1 s^2, 2 s^2, ^* 2 s^2, 2 p_z^2 ( 2 p_x^2 2 p_y^2 ), & BO = 1 2 (10-7)= 3 2 =1.5 ( ^* 2 p_x^2 ^* 2 p_y^1 ) aligned Thus, the correct order of decreasing bond order is C ₂²⁻> O ₂⁺> O ₂⁻> He ₂⁺

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