COMEDK20269 May 2026Morning ShiftChemistryGeneral Organic ChemistryActual
Lassaigne's test for the detection of nitrogen fails in
Options
- ANH ₂ CONH ₂
- BNH ₂ - NH ₂ HCl
- CNH ₂ CONHNH ₂ HCl
- DC ₆ H ₅ NHNH ₂ HCl
Correct answer
B. NH ₂ - NH ₂ HCl
Step-by-step solution
Lassaigne's test for the detection of nitrogen involves the fusion of the organic compound with sodium metal to form sodium cyanide ( NaCN ). For the formation of cyanide ion ( CN ⁻ ), both carbon and nitrogen must be present in the organic compound. Hydrazine hydrochloride ( NH ₂ -NH ₂ HCl ) does not contain carbon. Therefore, it cannot form sodium cyanide upon fusion with sodium metal, and Lassaigne's test for nitrogen fails. The other compounds ( NH ₂ CONH ₂ , NH ₂ CONHNH ₂ HCl , and C ₆ H ₅ NHNH ₂ HCl ) contain