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COMEDK2013ChemistryHaloalkanes and Haloarenes

Which of the following statements is incorrect regarding benzyl chloride?

Options

  1. AIt gives white precipitate with alcoholic AgNO ₃ .
  2. BIt is an aromatic compound with substitution in the side chain.
  3. CIt undergoes nucleophilic substitution reaction.
  4. DIt is less reactive than vinyl chloride.

Correct answer

D. It is less reactive than vinyl chloride.

Step-by-step solution

Benzyl chloride is more reactive than vinyl chloride as benzyl carbocation is stabilised by resonance. While, in vinyl chloride due to partial double bond character became of resonance, the C - Cl bond strength increases. Hence, reactivity of vinyl chloride decreases.

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