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COMEDK202510 May 2025Morning ShiftChemistryHydrocarbonsActual

An unsaturated hydrocarbon [ A ] undergoes the following series of reactions. Identify [ A ] .

Options

  1. ABut-1-yne
  2. BBut-2-yne
  3. CBut-2-ene
  4. DPropyne.

Correct answer

B. But-2-yne

Step-by-step solution

The hydrocarbon [A] reacts with ammoniacal AgNO₃ to give no reaction, which indicates that it is not a terminal alkyne. This eliminates but-1-yne and propyne. The reaction of [A] with Na/liquid NH₃ gives a trans product, which is a characteristic reaction of internal alkynes to form trans-alkenes. This suggests [A] is an internal alkyne. The reaction of [A] with alkaline KMnO₄ at 383 K yields 2 moles of a carboxylic acid with formula C₂H₄O₂ , which is acetic acid ( CH₃COOH ). This implies that the oxidative cleavag

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