Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
COMEDK2023Evening ShiftChemistryHydrocarbonsActual

Identify the reagents X , Y and Z used to bring out the following reactions.

Options

  1. AX = H ₂ O ₂ Y = Conc. HCl Z = O ₃
  2. BX = DIBAL- H Y = Conc. HNO ₃ Z = CrO ₂ Cl ₂
  3. CX = Air Y = dil. H ₂ SO ₄ Z = Cr ₂ O ₇ ²⁻ / H ⁺
  4. DX = Alkaline KMnO ₄ Y = dil HCl Z = CrO ₃

Correct answer

C. X = Air Y = dil. H ₂ SO ₄ Z = Cr ₂ O ₇ ²⁻ / H ⁺

Step-by-step solution

The conversion of 2-phenylpropane (cumene) to phenol ( C₆H₅OH ) is a standard industrial process known as the cumene process. In this process, cumene is first oxidized to cumene hydroperoxide using air (or O₂ ), followed by acid-catalyzed cleavage using dilute H₂SO₄ to yield phenol and acetone. Thus, X = Air and Y = dil. H₂SO₄ . The second step involves the oxidation of phenol to p-benzoquinone. This transformation is typically achieved using strong oxidizing agents such as chromic acid ( H₂CrO₄ ) or dichromate ion

Practice Hydrocarbons on Quantrex Academy →

More from Hydrocarbons

What is the major product [ P₃ ] formed when n- Hexane undergoes the given series of reactions: n-Hexane V₂O₅; 20 atm, 773k [ P ₁] C₂H₅Cl, Anhyd.AlCl₃; [ P ₂] Conc.HNO₃ + H₂SO₄; 33 2026The statements given below contains assertion and reason. Choose the correct option Assertion (A): Propene reacts with HBr in presence of organic peroxide gives 1-bromopropane. Rea 2026The product formed in the following reaction is: 2026Arrange the given alkanes in increasing order of their boiling points. (A) 2, 2-dimethylpropane (B) 2-methylbutane (C) n -pentane (D) n -butane 2026Select the reagents needed to convert Benzene to 4–Bromophenylpropene in the correct sequential order. (A). Cl ₂/ (B). ( CH ₃)₂ -CHCl /anhyd. AlCl ₃ (C). Alc. KOH (D). Br ₂ / Fe 2026The decreasing order of reactivity towards electrophilic substitutions is: 2026A compound with molecular formula C ₅ H ₁₀ that gives acetone on ozonolysis is: 2026When 2-butyne is treated with dilute H ₂ SO ₄/ HgSO ₄ , the product formed is: 2026 Full Hydrocarbons list All COMEDK PYQs