COMEDK2023Morning ShiftChemistryHydrocarbonsActual
Ammoniacal silver nitrate forms a white precipitate easily with
Options
- ACH ₃ CH = CH ₂
- BCH ₃ C = CCH ₃
- CCH ₃ C = CH
- DCH ₂= CH ₂
Correct answer
C. CH ₃ C = CH
Step-by-step solution
Ammoniacal silver nitrate, also known as Tollens reagent, reacts with terminal alkynes to form a white precipitate of silver acetylide. The general reaction is R-C CH + [Ag(NH₃)₂]^+ OH^- R-C C-Ag + 2NH₃ + H₂O . Among the given options, CH ₃ C CH (propyne) is a terminal alkyne, meaning it has an acidic hydrogen atom attached to the triply bonded carbon. The other compounds, CH ₃ CH = CH ₂ (propene), CH ₃ C CCH₃ (but-2-yne, an internal alkyne), and CH ₂= CH ₂ (ethene), do not possess an acidic terminal hydrogen atom