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COMEDK2021ChemistryHydrogen

Arrange the hydrides of group 15 in correct decreasing order of reducing nature.

Options

  1. ANH ₃ < PH ₃ < AsH ₃ < SbH ₃ < BiH ₃
  2. BNH ₃> PH ₃> AsH ₃> SbH ₃> BiH ₃
  3. CPH ₃ < AsH ₃ < SbH ₃ < BiH ₃ < NH ₃
  4. DBiH ₃> SbH ₃> AsH ₃> PH ₃> NH ₃

Correct answer

D. BiH ₃> SbH ₃> AsH ₃> PH ₃> NH ₃

Step-by-step solution

The reducing nature of the hydrides of group 15 elements depends on the stability of the M-H bond. As we move down the group from N to Bi, the atomic size of the central atom increases, which leads to a decrease in the bond dissociation enthalpy of the M-H bond. The bond strength decreases in the order NH ₃ > PH ₃ > AsH ₃ > SbH ₃ > BiH ₃ . Since the reducing character is directly proportional to the ease of releasing hydrogen atoms, the reducing nature increases as the bond strength decreases. Therefore, the correc

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