COMEDK2021ChemistryHydrogen
Arrange the hydrides of group 15 in correct decreasing order of reducing nature.
Options
- ANH ₃ < PH ₃ < AsH ₃ < SbH ₃ < BiH ₃
- BNH ₃> PH ₃> AsH ₃> SbH ₃> BiH ₃
- CPH ₃ < AsH ₃ < SbH ₃ < BiH ₃ < NH ₃
- DBiH ₃> SbH ₃> AsH ₃> PH ₃> NH ₃
Correct answer
D. BiH ₃> SbH ₃> AsH ₃> PH ₃> NH ₃
Step-by-step solution
The reducing nature of the hydrides of group 15 elements depends on the stability of the M-H bond. As we move down the group from N to Bi, the atomic size of the central atom increases, which leads to a decrease in the bond dissociation enthalpy of the M-H bond. The bond strength decreases in the order NH ₃ > PH ₃ > AsH ₃ > SbH ₃ > BiH ₃ . Since the reducing character is directly proportional to the ease of releasing hydrogen atoms, the reducing nature increases as the bond strength decreases. Therefore, the correc