COMEDK2023Morning ShiftChemistryStates of MatterActual
The behaviour of real gas approaches ideal behaviour at
Options
- Alow temperature, low pressure
- Blow pressure, high temperature
- Chigh pressure, low temperature
- Dhigh temperature, high pressure
Correct answer
B. low pressure, high temperature
Step-by-step solution
The equation of state for a real gas is given by the van der Waals equation: (P + an^2 V^2 )(V - nb) = nRT . For a real gas to approach ideal gas behaviour, the intermolecular forces of attraction must be negligible and the volume occupied by the gas molecules must be negligible compared to the total volume of the container. The term an^2 V^2 becomes negligible when the pressure P is very low, as the volume V becomes very large. Similarly, the term nb becomes negligible compared to V at low pressures and high tempe