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IAT IISER2026ChemistryChemical Bonding and Molecular Structure

Which one of the following molecules shows an increase in bond order after loss of an electron from the highest occupied molecular orbital?

Options

  1. AN ₂
  2. BC ₂
  3. CF ₂
  4. DB ₂

Correct answer

C. F ₂

Step-by-step solution

Bond order is given by 1 2 (N_b - N_a) . If an electron is removed from an antibonding molecular orbital, N_a decreases, resulting in an increase in bond order. If it is removed from a bonding molecular orbital, N_b decreases, resulting in a decrease in bond order. The molecular orbital electronic configurations are: F ₂ (18 electrons): _ 1s ² _ 1s ^ *2 _ 2s ² _ 2s ^ *2 _ 2p_z ² _ 2p_x ² _ 2p_y ² _ 2p_x ^ *2 _ 2p_y ^ *2 The highest occupied molecular orbital (HOMO) is _ 2p ^ * , which is antibonding. Loss of an ele

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