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AP EAMCET2008ChemistryBiomolecules

Hydrolysis of sucrose with dilute aqueous sulphuric acid yields

Options

  1. A1: 1 D-(+)-glucose; D-(-)-fructose
  2. B1 : 2 D-(+)-glucose; D-(-)-fructose
  3. C1: 1 D-(-)-glucose; D-(+)-fructose
  4. D1: 2 D-(-)-glucose; D-(+)-fructose

Correct answer

A. 1: 1 D-(+)-glucose; D-(-)-fructose

Step-by-step solution

On hydrolysis with dilute aqueous sulphuric acid, sucrose gives a equimolar mixture of D-(+) glucose and D-(-)-fructose. C ₁₂ H ₂₂ O ₁₁+ H ₂ O H ₂ SO ₄ sucrose C ₆ H ₁₂ O ₆+ C ₆ H ₁₂ O ₆ D-(+) glucose D-(-) fructose 1 : 1 arter hydrolysis Sucrose is dextrorotatory but after hydrolysis gives dextrorotatory and laevorotatory fructose, laevorotatory fructose is more, so the mixture is laevorotatory.

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