AP EAMCET2008ChemistryBiomolecules
Hydrolysis of sucrose with dilute aqueous sulphuric acid yields
Options
- A1: 1 D-(+)-glucose; D-(-)-fructose
- B1 : 2 D-(+)-glucose; D-(-)-fructose
- C1: 1 D-(-)-glucose; D-(+)-fructose
- D1: 2 D-(-)-glucose; D-(+)-fructose
Correct answer
A. 1: 1 D-(+)-glucose; D-(-)-fructose
Step-by-step solution
On hydrolysis with dilute aqueous sulphuric acid, sucrose gives a equimolar mixture of D-(+) glucose and D-(-)-fructose. C ₁₂ H ₂₂ O ₁₁+ H ₂ O H ₂ SO ₄ sucrose C ₆ H ₁₂ O ₆+ C ₆ H ₁₂ O ₆ D-(+) glucose D-(-) fructose 1 : 1 arter hydrolysis Sucrose is dextrorotatory but after hydrolysis gives dextrorotatory and laevorotatory fructose, laevorotatory fructose is more, so the mixture is laevorotatory.