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JEE Main 202330 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
30 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Environmental Chemistry

JEE Main 2023 · 30 January · Morning Shift · Chemistry · Environmental Chemistry

Formation of photochemical smog involves the following reaction in...

Formation of photochemical smog involves the following reaction in which A,BA, B and CC are respectively.

(i) NO2⟶huA+B{NO}_{2}\overset{hu}{⟶}A + B

(ii) B+O2→CB + {O}_{2} \to C

(iii) A+C→NO2+O2A + C \to {NO}_{2} + {O}_{2}

Choose the correct answer from the options given below:

Options

  1. AO,NOO, NO and NO3−{NO}_{3}^{-}
  2. BO,N2OO, {N}_{2}O and NONO
  3. CN,O2N, {O}_{2} and O3{O}_{3}
  4. DNO,ONO, O and O3{O}_{3}

Correct answer

D. NO,ONO, O and O3{O}_{3}

Step-by-step solution

When fossil fuels are burnt, a variety of pollutants are emitted into the earth’s troposphere. When these pollutants build up to sufficiently high levels, a chain reaction occurs from their interaction with sunlight in which NONO is converted into nitrogen dioxide (NO2{NO}_{2}). This NO2{NO}_{2} in turn absorbs energy from sunlight and breaks up into nitric oxide and free oxygen atom.

{NO2(g)→hvNO(g)+O(g)(A)(B)−−−−−(i)\begin{cases}{NO}_{2} ( g ) & \overset{hv}{\to} & NO ( g ) & + & O ( g ) \\ & & \left(A\right) & & \left(B\right)\end{cases} - - - - - ( i )

Oxygen atoms are very reactive and combine with the O2{O}_{2} in air to produce ozone.

{O(g)+O2(g)⇌O3(g)(B)(C)−−−−−(ii)\begin{cases}O ( g ) & + & {O}_{2} ( g ) & ⇌ & {O}_{3} ( g ) \\ \left(B\right) & & & & \left(C\right)\end{cases} - - - - - ( ii )

The ozone formed in the above reaction (ii) reacts rapidly with the NO(g)NO ( g ) formed in reaction (i) to regenerate NO2{NO}_{2} . NO2{NO}_{2} is a brown gas and at sufficiently high levels can contribute to haze.

{NO(g)+O3(g)→NO2(g)+(A)(C)\begin{cases}NO ( g ) & + & {O}_{3} ( g ) & \to & {NO}_{2} ( g ) & + \\ \left(A\right) & & \left(C\right) & & & \end{cases}O2(g)\begin{array}{ll}{O}_{2} ( g )\end{array}−−−−(iii)- - - - ( iii )

So, the A, B and C are NO,OandO3NO, O\text{and}{O}_{3} respectively.

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