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JEE Main 202229 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
29 June
Shift
Evening Shift
Subject
Chemistry
Chapter
Environmental Chemistry

JEE Main 2022 · 29 June · Evening Shift · Chemistry · Environmental Chemistry

Sulphur dioxide is one of the components of polluted air. SO _ 2 is...

Sulphur dioxide is one of the components of polluted air. SO2{SO}_{2} is also a major contributor to acid rain. The correct and complete reaction to represent acid rain caused by SO2{SO}_{2} is :

Options

  1. A2SO2+O2→2SO32{SO}_{2} + {O}_{2} \to 2{SO}_{3}
  2. BSO2+O3→SO3+O2{SO}_{2} + {O}_{3} \to {SO}_{3} + {O}_{2}
  3. CSO2+H2O2→H2SO4{SO}_{2} + {H}_{2}{O}_{2} \to {H}_{2}{SO}_{4}
  4. D2SO2+O2+2H2O→2H2SO42{SO}_{2} + {O}_{2} + 2{H}_{2}O \to 2{H}_{2}{SO}_{4}

Correct answer

D. 2SO2+O2+2H2O→2H2SO42{SO}_{2} + {O}_{2} + 2{H}_{2}O \to 2{H}_{2}{SO}_{4}

Step-by-step solution

Acid rain is a by product of a variety of human activities that emit the oxides of sulphur and nitrogen in the atmosphere. As mentioned earlier, burning of fossil fuels (which contain sulphur and nitrogenous matter) such as coal and oil in power stations and furnaces or petrol and diesel in motor engines produce sulphur dioxide and nitrogen oxides. SO2{SO}_{2} and NO2{NO}_{2} after oxidation and reaction with water are major contributors to acid rain, because polluted air usually contains particulate matter that catalyse the oxidation.

2SO2(g)+O2(g)+2H2O(l)→2H2SO4(aq)2{SO}_{2}\left(g\right) + {O}_{2}\left(g\right) + 2{H}_{2}O\left(l\right) \to 2{H}_{2}{SO}_{4}\left(aq\right)

4NO2(g)+O2(g)+2H2O(l)→4HNO3(aq)4{NO}_{2}\left(g\right) + {O}_{2}\left(g\right) + 2{H}_{2}O\left(l\right) \to 4{HNO}_{3}\left(aq\right)

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