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JEE Main 202312 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
12 April
Shift
Morning Shift
Subject
Chemistry
Chapter
General Principles and Processes of Isolation of Metals

JEE Main 2023 · 12 April · Morning Shift · Chemistry · General Principles and Processes of Isolation of Metals

Given below are two statements: one is labelled as Assertion A and...

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R

Assertion A: In the Ellingham diagram, a sharp change in slope of the line is observed from Mg→MgOMg \to MgO at  1120oC~ {1120}^{o}C

Reason R: There is a large change of entropy associated with the change of state

In the light of the above statements, choose the correct answer from the options given below

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R Assertion A: In

Options

  1. ABoth A and R are true but R is NOT the correct explanation of A
  2. BA is false but R is true
  3. CBoth A and R are true and R is the correct explanation of A
  4. DA is true but R is false

Correct answer

C. Both A and R are true and R is the correct explanation of A

Step-by-step solution

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R Assertion A: In

For line II ∆S∆ S is more negative than line I. In the Ellingham diagram, a sharp change in slope of the line is observed for Mg−MgOMg - MgO at  1120oC~ {1120}^{o}C because that is the boiling point of magnesium.

From diagram, ∆SI=(Ssolid)−(Ssolid+Sgas)∆SII=(Sliquid)−(Ssolid+Sgas)∆ {S}_{I} = ( {S}_{solid} ) - ( {S}_{solid} + {S}_{gas} ) ∆ {S}_{II} = ( {S}_{liquid} ) - ( {S}_{solid} + {S}_{gas} )

There is a large increase in entropy associated with the change of state of magnesium.

So, both Assertion (A) and Reason (R) are true and (R) is the correct explanation of (A).

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