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A sample of atomic hydrogen gas is irradiated by a beam of ultraviolet radiation having a wavelength between 100 nm and 200 nm . Assuming that the atoms are in the ground state, the wavelength which will have low intensity in the transmitted beam is

Options

  1. A104 nm
  2. B103 nm
  3. C105 nm
  4. D100 nm

Correct answer

B. 103 nm

Step-by-step solution

The energy of a photon corresponding to λ = 100 nm is, 1 2 4 2 eV nm 1 0 0 nm = 1 2 · 4 2 eV Similarly, the corresponding to λ = 200 nm is 6 . 21 eV . The energy needed to take the atom from the ground state to the first excited state is E 2 - E 1 = 13 . 6 eV - 3 . 4 eV = 10 . 2 eV The energy needed to take the atom from the ground state to the second excited state is E 3 - E 1 = 13 . 6 eV - 1 . 5 eV = 12 . 1 eV The energy needed to take the atom from the ground state to the third excited state is E 4 - E 1 = 13 .

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