Fundamentals of Organic ChemistryChemistryAlcohols Phenols and Ethers
Identify the appropriate reagent for the following chemical transformation:
Options
- ANaCl
- BCl ₂
- CNa ₂ Cr ₂ O ₇
- DHCl
Correct answer
D. HCl
Step-by-step solution
The given reaction is a nucleophilic substitution where the hydroxyl group ( -OH ) of an alcohol is replaced by a chloride ion ( -Cl ) to form an alkyl chloride and water ( H₂O ). Evaluating the given options: NaCl: Cannot substitute the -OH group directly because hydroxide ( -OH^- ) is a poor leaving group. Cl₂ : Does not react with alcohols to form alkyl chlorides; it is typically used for the halogenation of alkanes or alkenes. Na₂Cr₂O₇ : A strong oxidizing agent that would oxidize the given secondary alcohol to