Fundamentals of Organic ChemistryChemistryAlcohols Phenols and Ethers
Identify the major products formed in the following reaction:
Correct answer
2
Step-by-step solution
The given reaction is the acid-catalyzed rearrangement of a hydroperoxide, known as the Hock rearrangement (similar to the cumene hydroperoxide rearrangement). The mechanism involves the protonation of the hydroperoxide - OH group, followed by the loss of a water molecule. This creates an electron-deficient oxygen atom, prompting the migration of one of the aryl groups from the adjacent carbon to the oxygen atom. The migratory aptitude of aryl groups depends on their electron-donating ability, as electron-donating