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Fundamentals of Organic ChemistryChemistryAldehydes and Ketones

Identify the major product of the following reaction:

Options

  1. ANone of these

Correct answer

A. None of these

Step-by-step solution

The given reaction is a Knoevenagel condensation between an active methylene compound and an aldehyde. Nitroacetonitrile ( NC - CH ₂- NO ₂ ) contains highly acidic -hydrogens due to the presence of two strong electron-withdrawing groups ( - CN and - NO ₂ ). The base, sodium ethoxide ( NaOEt ), abstracts an -proton to form a resonance-stabilized carbanion: NC - CH ₂- NO ₂ + EtO ^- NC - CH ^-- NO ₂ + EtOH This carbanion acts as a nucleophile and attacks the electrophilic carbonyl carbon of benzaldehyde ( Ph - CHO ),

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