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Fundamentals of Organic ChemistryChemistryAldehydes and Ketones

Identify the appropriate reagent required to carry out the following transformation:

Options

  1. AHOCH ₂ CH ₂ OH
  2. BCH ₃ CH ₂ OH
  3. CCH ₃ OH
  4. DCH ₃ COCH ₃

Correct answer

A. HOCH ₂ CH ₂ OH

Step-by-step solution

The given reaction shows the conversion of a ketone (acetophenone) into a cyclic ketal. The formation of a cyclic ketal with a five-membered ring requires the reaction of the carbonyl compound with a 1,2-diol. Observing the structure of the product, the ketal part consists of a - O - CH ₂- CH ₂- O - group attached to the original carbonyl carbon. This indicates that the reagent used is ethylene glycol, HOCH ₂ CH ₂ OH . The reaction takes place in the presence of a catalytic acid, and water is removed to drive the e

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