Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
Fundamentals of Organic ChemistryChemistryAldehydes and Ketones

Fehling's solution can be used to distinguish between which of the following pairs of compounds?

Options

  1. ANone of the above pairs
  2. BCH ₃ CHO and CH ₃ COCH ₂ OH
  3. CBoth of the above pairs
  4. DCH ₃ CHO and C ₆ H ₅ CHO

Correct answer

D. CH ₃ CHO and C ₆ H ₅ CHO

Step-by-step solution

Fehling's solution is a mild oxidizing agent used to differentiate aliphatic aldehydes from aromatic aldehydes and ketones. Aliphatic aldehydes like CH ₃ CHO reduce Fehling's solution to form a red precipitate of Cu ₂ O . Aromatic aldehydes like C ₆ H ₅ CHO do not reduce Fehling's solution. -hydroxy ketones like CH ₃ COCH ₂ OH also reduce Fehling's solution because they tautomerize into an enediol intermediate in the alkaline medium, which then gets oxidized. Thus, both CH ₃ CHO and CH ₃ COCH ₂ OH give a positive F

Practice Aldehydes and Ketones on Quantrex Academy →

More from Aldehydes and Ketones

All Aldehydes and Ketones questions Full Aldehydes and Ketones list All Fundamentals of Organic Chemistry PYQs