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Fundamentals of Organic ChemistryChemistryAldehydes and Ketones

Identify the appropriate reagent for the following transformation.

Options

  1. AHOCH ₂ CH ₂ OH
  2. BCH ₃ COCH ₃
  3. CCH ₃ OH
  4. DCH ₃ CH ₂ OH

Correct answer

D. CH ₃ CH ₂ OH

Step-by-step solution

The given transformation is the conversion of a ketone (acetophenone) into a ketal. The product is a diethyl ketal, as it contains two ethoxy ( - OCH₂CH₃ ) groups attached to the same carbon atom. Ketal formation occurs when a ketone reacts with two equivalents of a monohydric alcohol in the presence of an acid catalyst. The general reaction is: R₂C=O + 2 R'OH R₂C(OR')₂ + H₂O Since the product has ethoxy groups, the required alcohol is ethanol ( CH₃CH₂OH ). The specific reaction is: C₆H₅COCH₃ + 2 CH₃CH₂OH C₆H₅C(OCH

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