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Fundamentals of Organic ChemistryChemistryAmines

Identify the major product formed in the following reaction sequence.

Correct answer

2

Step-by-step solution

The given reaction sequence involves two steps: Aniline reacts with a mixture of NaNO ₂ and HCl at low temperatures ( 0-5^ C ) to undergo diazotization. This forms benzene diazonium chloride. C ₆ H ₅ NH ₂ NaNO ₂, HCl C ₆ H ₅ N ₂^+ Cl ^- The benzene diazonium chloride is then treated with copper(I) bromide ( CuBr ). This is a Sandmeyer reaction, where the diazonium group is replaced by a bromide ion, releasing nitrogen gas. C ₆ H ₅ N ₂^+ Cl ^- CuBr C ₆ H ₅ Br + N ₂ The final major product is bromobenzene.

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