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Fundamentals of Organic ChemistryChemistryAmines

Identify the compounds B , X , and R respectively in the following sequences of reactions: (i) C ₂ H ₅ MgBr ClCN A H ₃ O ⁺ B (ii) CH ₃ COCH ₃ [ NaOH ] I ₂ X Ag Y (iii) C ₆ H ₅ NH ₂ [ HCl ] NaNO ₂ P CuCN Q +4 H R

Options

  1. AC ₂ H ₅ CH ₂ NH ₂ , CH ₃ I , C ₆ H ₅ COOH
  2. BC ₂ H ₅ COOH , C ₂ H ₅ I , C ₆ H ₅ CONH ₂
  3. CC ₂ H ₅ COOH , CHI ₃ , C ₆ H ₅ CH ₂ NH ₂
  4. DC ₂ H ₅ COOH , CH ₃ I , C ₆ H ₅ COOH

Correct answer

C. C ₂ H ₅ COOH , CHI ₃ , C ₆ H ₅ CH ₂ NH ₂

Step-by-step solution

In sequence (i), the reaction of ethyl magnesium bromide with cyanogen chloride yields propanenitrile (A). C ₂ H ₅ MgBr + ClCN C ₂ H ₅ CN + MgBrCl Hydrolysis of propanenitrile in an acidic medium yields propanoic acid (B). C ₂ H ₅ CN H ₃ O ⁺ C ₂ H ₅ COOH In sequence (ii), acetone undergoes the iodoform reaction with iodine and sodium hydroxide to form iodoform (X) and sodium acetate. CH ₃ COCH ₃ [ NaOH ] I ₂ CHI ₃ + CH ₃ COONa Heating iodoform with silver powder yields acetylene (Y). 2 CHI ₃ Ag CH CH In sequence (i

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