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Fundamentals of Organic ChemistryChemistryBiomolecules

Glucose gives a positive silver mirror test with ammoniacal silver nitrate because it contains:

Options

  1. Aa vicinal diol group
  2. Ba ketone group
  3. Can aldehyde group
  4. Da hydroxy group

Correct answer

C. an aldehyde group

Step-by-step solution

Tollens' reagent is an ammoniacal silver nitrate solution, which acts as a mild oxidizing agent. It is used to distinguish aldehydes from ketones, as it oxidizes aldehydes to corresponding carboxylate ions and gets reduced to metallic silver, forming a silver mirror on the inner walls of the test tube. Glucose is an aldohexose, meaning its open-chain structure contains an aldehyde group ( -CHO ) at the C₁ position. Due to the presence of this aldehyde group, glucose readily reduces Tollens' reagent and gives a posi

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