Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
Fundamentals of Organic ChemistryChemistryBiomolecules

Fructose reduces Fehling's solution due to the presence of:

Options

  1. Aa hydroxy group
  2. Ban aldehyde group
  3. Can -hydroxyketone group
  4. Da ketone group

Correct answer

C. an -hydroxyketone group

Step-by-step solution

Fructose is a ketose sugar containing an -hydroxyketone group. Under the alkaline conditions of Fehling's solution, the -hydroxyketone group undergoes tautomerization (Lobry de Bruyn-van Ekenstein transformation) to form an enediol intermediate. This intermediate further converts into an aldose (glucose and mannose) which contains an aldehyde group. The newly formed aldehyde group then reduces Fehling's solution. Thus, the reducing property of fructose is due to the presence of the -hydroxyketone group. Answer: an

Practice Biomolecules on Quantrex Academy →

More from Biomolecules

All Biomolecules questions Full Biomolecules list All Fundamentals of Organic Chemistry PYQs