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Fundamentals of Organic ChemistryChemistryCarboxylic Acid Derivatives

Which of the following compounds has the highest boiling point?

Options

  1. ACH ₃ CH ₂ OH
  2. BCH ₃ CO ₂ H
  3. CCH ₃ COCH ₃
  4. DCH ₃ CH ₂ CH ₃

Correct answer

B. CH ₃ CO ₂ H

Step-by-step solution

The boiling point of a compound depends on the strength of its intermolecular forces. CH ₃ CH ₂ CH ₃ (Propane) is non-polar and has only weak London dispersion forces, resulting in the lowest boiling point. CH ₃ COCH ₃ (Acetone) is polar and has dipole-dipole interactions, giving it a higher boiling point than propane but lower than compounds with hydrogen bonding. CH ₃ CH ₂ OH (Ethanol) and CH ₃ CO ₂ H (Acetic acid) both exhibit intermolecular hydrogen bonding. Acetic acid has stronger hydrogen bonding than ethano

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