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Fundamentals of Organic ChemistryChemistryCarboxylic Acid Derivatives

When benzene is treated with acetic anhydride in the presence of anhydrous aluminium chloride at 80^ C , the major product formed is:

Options

  1. ABenzoic acid
  2. BAcetophenone
  3. CBenzophenone
  4. DEthyl phenyl ketone

Correct answer

B. Acetophenone

Step-by-step solution

The reaction of benzene with acetic anhydride in the presence of anhydrous aluminium chloride is an example of Friedel-Crafts acylation. The electrophile generated is the acetyl cation ( CH₃C^+O ). Benzene undergoes electrophilic aromatic substitution with the acetyl cation to form acetophenone. The chemical equation is: C₆H₆ + (CH₃CO)₂O AlCl₃ C₆H₅COCH₃ + CH₃COOH The major product formed is acetophenone. Answer: Acetophenone

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