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Fundamentals of Organic ChemistryChemistryCarboxylic Acid Derivatives

Identify the major product formed in the following reaction:

Correct answer

1

Step-by-step solution

The given reactant is phthalic acid (benzene-1,2-dicarboxylic acid). The reagent P₂O₅ (phosphorus pentoxide) acts as a strong dehydrating agent. When phthalic acid is heated with P₂O₅ , it undergoes intramolecular dehydration. A molecule of water ( H₂O ) is eliminated from the two adjacent carboxylic acid ( -COOH ) groups. This elimination leads to the formation of a five-membered cyclic anhydride ring fused to the benzene ring. The resulting major product is phthalic anhydride. The structure of phthalic anhydride

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