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Fundamentals of Organic ChemistryChemistryGeneral Organic Chemistry

Identify the correct decreasing order of the number of enolizable protons for the following compounds: (I) (II) (III)

Options

  1. AI > II > III
  2. BI > III > II
  3. CII > III > I
  4. DIII > I > II

Correct answer

D. III > I > II

Step-by-step solution

The number of enolizable protons in a compound is equal to the number of hydrogen atoms attached to the -carbon(s) adjacent to the carbonyl group. 1. Compound (I) is acetaldehyde ( CH ₃ CHO ). It has one -carbon (the methyl group) which is attached to 3 hydrogen atoms. Thus, it has 3 enolizable protons. 2. Compound (II) is -valerolactone (a cyclic ester). The carbonyl group is adjacent to an oxygen atom on one side and a CH ₂ group on the other side. The -carbon has 2 hydrogen atoms. Thus, it has 2 enolizable proto

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