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Fundamentals of Organic ChemistryChemistryGeneral Organic Chemistry

Which of the following compounds has the highest boiling point?

Options

  1. ACH ₃ CO ₂ H
  2. BCH ₃ COCH ₃
  3. CCH ₃ CH ₂ OH
  4. DCH ₃ OCH ₃

Correct answer

A. CH ₃ CO ₂ H

Step-by-step solution

The boiling point of a compound depends on the strength of its intermolecular forces. CH ₃ CO ₂ H (acetic acid) has an - OH group and a C=O group, allowing it to form strong intermolecular hydrogen bonds. It exists as a dimer in the liquid phase, which significantly increases its boiling point. CH ₃ CH ₂ OH (ethanol) also exhibits intermolecular hydrogen bonding, but the extent and strength of hydrogen bonding are lesser than in acetic acid. CH ₃ COCH ₃ (acetone) has dipole-dipole interactions but lacks the ability

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