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Fundamentals of Organic ChemistryChemistryGeneral Organic Chemistry

Identify the correct order of acidic strength for the following compounds: (i) (ii) (iii)

Options

  1. A(ii) > (iii) > (i)
  2. B(i) > (ii) > (iii)
  3. C(iii) > (i) > (ii)
  4. D(i) > (iii) > (ii)

Correct answer

A. (ii) > (iii) > (i)

Step-by-step solution

The acidic strength of unsaturated carboxylic acids is determined by the stability of their conjugate base (carboxylate anion). Electron-withdrawing groups stabilize the carboxylate anion via the -I effect, increasing acidity. Electron-donating groups destabilize the anion via the +I effect, decreasing acidity. In compound (ii), the - Cl atom exerts a strong -I effect. Being cis to the - COOH group, it effectively stabilizes the conjugate base, making compound (ii) the most acidic. Compound (iii) has one - CH ₃ gro

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