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Fundamentals of Organic ChemistryChemistryGeneral Organic Chemistry

Which of the following species is NOT a carbene?

Options

  1. A: CCl ₃
  2. B: CH ₂
  3. C: CCl ₂

Correct answer

B. : CH ₂

Step-by-step solution

A carbene is defined as a neutral, divalent carbon species containing two unshared valence electrons. Its general formula is :CR₂ . Let us evaluate the given options: (A) The image represents bromochlorocarbene ( :C(Br)(Cl) ), which has a divalent carbon with a lone pair. It is a carbene. (B) : CCl ₃ represents a carbon atom bonded to three chlorine atoms along with a lone pair. This makes the carbon trivalent with an octet, which corresponds to the trichloromethyl carbanion ( CCl ₃⁻ ) rather than a neutral carbene

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