Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
Fundamentals of Organic ChemistryChemistryGeneral Organic Chemistry

Identify the correct stability order for the following carbocations: (I) (II) (III)

Options

  1. A(I) > (III) > (II)
  2. B(III) > (II) > (I)
  3. C(II) > (III) > (I)
  4. D(I) > (II) > (III)

Correct answer

D. (I) > (II) > (III)

Step-by-step solution

The stability of the given benzylic carbocations depends on the electron-donating ability of the group attached at the para position. The cyclopropyl group acts as a strong electron donor through - conjugation. The presence of electron-donating methyl groups on the cyclopropyl ring increases the electron density within the ring due to their +I effect. This enhances the overall electron-donating ability of the cyclopropyl group towards the benzene ring, which in turn stabilizes the benzylic carbocation. Carbocation

Practice General Organic Chemistry on Quantrex Academy →

More from General Organic Chemistry

All General Organic Chemistry questions Full General Organic Chemistry list All Fundamentals of Organic Chemistry PYQs