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Fundamentals of Organic ChemistryChemistryGeneral Organic Chemistry

Identify the correct order of stability for the following quinones: I. II. III.

Options

  1. AIII > I > II
  2. BI > III > II
  3. CI = III > II
  4. DI = II > III

Correct answer

B. I > III > II

Step-by-step solution

The given compounds are: I. p-benzoquinone II. o-benzoquinone III. diphenoquinone In p-benzoquinone (I), the two carbonyl groups are at the para position. Their dipoles are directed opposite to each other, which minimizes dipole-dipole repulsion, making it quite stable. In o-benzoquinone (II), the two carbonyl groups are adjacent (ortho position). This causes strong dipole-dipole repulsion, making it highly unstable and reactive. In diphenoquinone (III), there are two quinonoid rings. The formation of this structur

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