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Fundamentals of Organic ChemistryChemistryHaloalkanes and Haloarenes

Identify the major product P in the following reaction: [ (ii) H ^ ] (i) HO ^ / P

Options

  1. ANone of these
  2. BBoth in equal proportions

Correct answer

A. None of these

Step-by-step solution

The given reaction is a nucleophilic aromatic substitution ( S_NAr ). The -NO₂ group is strongly electron-withdrawing and activates the benzene ring towards nucleophilic attack at the ortho and para positions. This is because the intermediate carbanion (Meisenheimer complex) is stabilized by resonance when the attack occurs at these positions. In the starting material (1,2-dichloro-4-nitrobenzene), the chlorine atom at position 1 is para to the -NO₂ group, whereas the chlorine atom at position 2 is meta to the -NO₂

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