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AP EAMCET202125 Aug 2021Evening ShiftChemistryClassification of Elements and Periodicity in PropertiesActual

The formation of oxide ion O ²⁻ from oxygen atom requires an exothermic reaction, followed by an endothermic step as shown below. The process of formation of O ²⁻ in gas phase is unfavorable ( H^ =+ . ve ) , even though it has stable configuration of the nearest noble gas neon. This is because aligned & O (g)+e⁻ O ⁻(g) ; H^ =-141 ~kJ ~mol ⁻¹ & O ⁻(g)+e⁻ O ²⁻(g) ; H^ =+760 ~kJ ~mol ⁻¹ aligned

Options

  1. AO ²⁻ has larger size than that of neon
  2. Boxygen is more electronegative than neon
  3. CO ²⁻ has larger size than oxygen atom
  4. Delectron repulsion in oxide ion is more which over comes the stability achieved by noble gas configuration.

Correct answer

D. electron repulsion in oxide ion is more which over comes the stability achieved by noble gas configuration.

Step-by-step solution

The process of formation of O ²⁻ in the gas phase is unfavorable even through O ²⁻ is isoelectronic with neon. It is due to that electronic repulsion outweighs the stability gained by achieving noble gas configuration. The formation of oxide ion, O ²⁻(g) from oxygen atom require first an exothermic and then endothermic step. aligned & O (g)+e⁻ O ⁻(g) ; H^ =-141 ~kJ ~mol ⁻¹ & O ⁻(g)+e⁻ O ²⁻(g) ; H^ =+760 ~kJ ~mol ⁻¹ aligned When an electron is added to O ⁻ anion, there is strong electrostatic repulsion between two n

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