AP EAMCET202017 Sep 2020Morning ShiftChemistryClassification of Elements and Periodicity in PropertiesActual
Assertion (A) Boron has a smaller first ionisation enthalpy than beryllium. Reason (R) The penetration of a (2 s )-electron to the nucleus is more than the (2 p )-electron hence, (2 p )-electron is more shielded by the inner core of electrons than (2 ~s )-electrons.
Options
- AAssertion and Reason both are correct statements but Reason is not correct explanation for Assertion.
- BAssertion is correct statement but Reason is wrong statement.
- CAssertion and Reason both are correct statements and Reason is correct explanation for Assertion.
- DAssertion and Reason both are wrong statements.
Correct answer
C. Assertion and Reason both are correct statements and Reason is correct explanation for Assertion.
Step-by-step solution
Assertion (A) Electronic configuration of boron ((Z=5) ) is [He] (2 s^2 2 p^1 ). So, in first ionisation ( (1 IE ₁ ) or ( _i H₁ ) ) removal will take place from unpaired (p^1 )-electron. Whereas that of Be will be from paired (2 s^2 )-electrons which requires more energy. Electronic configuration of ( Be (Z=4):[ He ] 2 s^2 ) So, the Assertion is a correct statement. Reason (R) (s )-orbital is being symmetrical in shape (spherical), it shields nuclear force (nuclear charge) strongly. So, (2 p^1 )-electron of (B ) is