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AP EAMCET202319 May 2023Morning ShiftChemistryHydrogenActual

Given below are two statements Assertion (A): Protium and deuterium differ in their rates of reactions. Reason (R): They have different enthalpies of bond dissociation. The correct answer is

Options

  1. ABoth (A) and (R) are correct and, (R) is the correct explanation of (A)
  2. BBoth (A) and (R) are correct but (R) is not the correct explanation of ( A )
  3. C(A) is correct but (R) is incorrect
  4. D(A) is incorrect but (R) is correct

Correct answer

A. Both (A) and (R) are correct and, (R) is the correct explanation of (A)

Step-by-step solution

H - H bond enthalpy =435.88 ~kJ ~mol ⁻¹ D - D bond enthalpy =443.35 ~kJ ~mol ⁻¹ . Due to a difference in their bond dissociation enthalpies, they undergo chemical reactions at different rates. Thus, both, (A) and (R) are true and (R) correctly explains (A).

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