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AP EAMCET202315 May 2023Evening ShiftChemistryp Block Elements (Group 13 & 14)Actual

Among the following the correct statements are I. Germanium exists only in traces II. PbF ₄ molecule is tetrahedral in shape III. GeX ₂ is more stable than GeX ₄

Options

  1. AII, III only
  2. BI, II only
  3. CI, II, III
  4. DI, III only

Correct answer

B. I, II only

Step-by-step solution

Statement I is correct as Ge and Sn exist on earth's crust in trace amounts ( 1-2 ppm ) . Statement II is correct as Pb belongs to group 14 and thus has four valence electrons out of which all four are used to make the four Pb - F bonds. The resultant geometry is tetrahedral. Statement III is incorrect as the stability of the +2 oxidation state increases down the group due to inert pair effect and is predominant for heavier elements. Ge prefers +4 state over +2 so Ge ₄ is more stable than Ge X ₂ .

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