AP EAMCET202123 Aug 2021Morning ShiftChemistryp Block Elements (Group 13 & 14)Actual
Consider the following reaction BCl ₃+ NH ₃ BCl ₃ NH ₃ The geometries of BCl ₃ and BCl ₃ NH ₃ respectively are
Options
- Atrigonal planar and tetrahedral
- Btetrahedral and square planar
- Ctetrahedral and trigonal bipyramidal
- Dsquare planar and trigonal pyramidal
Correct answer
A. trigonal planar and tetrahedral
Step-by-step solution
The molecular geometry of BCl ₃ is trigonal planar. In BCl ₃ NH ₃ , the central atom B has 6 valence electrons that makes it an electron deficient molecule. BCl ₃ acts as a Lewis acid as it needs 2 electrons to complete its octet. NH ₃ can donate its lone pair to boron as it acts as Lewis acid. The resulting structure is tetrahedral.